Ideal Gas Law
Relate the pressure, volume, amount and temperature of a gas. Fill in any three and solve for the fourth, in the units you prefer.
What is an Ideal Gas?
An ideal gas is a model in which molecules are tiny points that only interact by bouncing off each other and the walls. Under everyday conditions real gases such as air, nitrogen and oxygen behave very close to this model.
The law combines three older discoveries: squeezing a gas raises its pressure (Boyle), heating it makes it expand (Charles), and equal volumes hold equal numbers of molecules (Avogadro). Temperature must always be in kelvin.
Live Graph
isothermGas Constant & Molar Volume
| Quantity | Value |
|---|---|
| R (SI) | 8.314 J/(mol·K) |
| R (litre·atm) | 0.08206 L·atm/(mol·K) |
| R (litre·bar) | 0.08314 L·bar/(mol·K) |
| R (litre·mmHg) | 62.36 L·mmHg/(mol·K) |
| Molar volume at STP (0 °C, 1 atm) | 22.414 L/mol |
| Molar volume at 25 °C, 1 bar | 24.79 L/mol |
| Avogadro constant NA | 6.022×1023 /mol |
Related Gas Laws
For a fixed amount of gas that changes from one state to another. Boyle’s, Charles’s and Gay-Lussac’s laws are special cases where one quantity stays constant.
Replace n by m/M to find the density of a gas from its molar mass. Heavier gases sink, which is why CO2 collects at floor level.
The van der Waals equation corrects for attraction between molecules (a) and their own volume (b). It matters at high pressure or close to condensation.
Sources & Verification
- S. S. Zumdahl & S. A. Zumdahl, Chemistry, 10th ed., Cengage, 2018 — Ch. 5 (Gases).
- P. Atkins & J. de Paula, Atkins’ Physical Chemistry, 11th ed., Oxford University Press, 2018 — Focus 1 (Gases).
- E. Tiesinga, P. J. Mohr, D. B. Newell & B. N. Taylor, “CODATA recommended values of the fundamental physical constants: 2018”, Reviews of Modern Physics 93, 025010 (2021) — values of the constants used.